There are some things about your question that suggest to me that you should do some reading on Calcium and Alkalinity supplementation methods. 
  I would recommend that you start at this article and go from there.
http://www.advancedaquarist.com/issues/feb2003/chem.htm
  Greatly simplified, you don't want to be adding an Alk supplement alone.  Generally speaking you need to add both Ca and Alk in a balanced way.  Using your A & B you were on the right track, but you likely added too much which showed itself as a high alkalinity.
 
		
	
		
		
		
		
			
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				400 gal reef.  Established April, 2007.  3 Sequence Dart, RM12-4 skimmer, 2 x OM4Ways,  Yellow Tang, Maroon Clown (pair), Blonde Naso Tang, Vlamingi Tang, Foxface Rabbit, Unicorn Tang, 2 Pakistani Butterflies and a few coral gobies
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