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#26
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![]() As a bit to add:
I was reading through Fishnets library and came across this from the Advanced Aquarist forum; <blockquote><font size="1" face="Verdana, Helvetica, sans-serif">quote Quote:
<blockquote><font size="1" face="Verdana, Helvetica, sans-serif">quote Quote:
<blockquote><font size="1" face="Verdana, Helvetica, sans-serif">quote:</font><hr> Bob –Given that Magnesium bonds tends to form on the xtals(crystals) of Calcium carbonate thus inhibiting their dissolution, is it not possible that the reduction of the total #s of CO3= in solution might decrease the pH? Randy Holmes-Farley - Whether it did that on it own as MgCO3 precipitation (or something else like Mg(OH)2), or on the surface of CaCO3, that is how I believe the pH would drop. Of course, in the test I ran there was no solid surface of CaCO3, but in a tank there would be. Buffering effect would not be changed for any period as the SO4= would stand in until the CO2 infusion would re balance.>> I don't agree with that. The buffering (alkalinity) will be depleted. This would be true whether you believe that hydroxide or carbonate or both were removed from the system. Even after reequilibration with CO2, the solution is permanently decreased in alkalinity, and will reequilibrate at a lower pH. <hr></blockquote> Just something else to consider. |
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