Well, honestly, I don't recall putting much thought into which went first, corals or fish. I think I probably added both at the same time. I'm not sure if it really makes that much of a difference in terms of reducing the likelihood of nipping. Nippers gonna nip :-)
In terms of fish alone, if you can plan ahead, then I think the general consideration of adding the more timid fish in first would apply. This allows them to get established. Mind you even this is no guarantee down the road. An aggressive fish will be aggressive, period.
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