What an incredibly nice sized tank to start with. Green with envy!!
First off, welcome to Canreef.
Then, make sure that your tank has fully cycled first before even contemplating lifestock!
Then, with your size tank, you need to decide what do you want to have: fish-only? large-polyped corals? Soft corals? or eventually a full-blown reef with small polyped stoney corals??
Sure you can give your fish away later, you still might have to, sometimes your fish just decides to misbehave and nibble on a clam or two. But you don't want a big wrasse/angel that may devour all your ohter stuff, etc...
Let us know what you may want to have as in the above questions, and then you should either get a couple of good books (you can borrow) to get you started.
What exciting times. Wish I was in your shoes, Nice skimmer, too.
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