There are some things about your question that suggest to me that you should do some reading on Calcium and Alkalinity supplementation methods.
I would recommend that you start at this article and go from there.
http://www.advancedaquarist.com/issues/feb2003/chem.htm
Greatly simplified, you don't want to be adding an Alk supplement alone. Generally speaking you need to add both Ca and Alk in a balanced way. Using your A & B you were on the right track, but you likely added too much which showed itself as a high alkalinity.
__________________
400 gal reef. Established April, 2007. 3 Sequence Dart, RM12-4 skimmer, 2 x OM4Ways, Yellow Tang, Maroon Clown (pair), Blonde Naso Tang, Vlamingi Tang, Foxface Rabbit, Unicorn Tang, 2 Pakistani Butterflies and a few coral gobies
My Tank:
http://www.canreef.com/vbulletin/showthread.php?t=28436