Placebo no, chemistry Yes. It sounds funny yes but really it is just a carbon source so is the sugar and many more. Vodka being distilled 3 times make it a very pure and concentrated source. You don't want the vodka with a fruity flavor. Like I said many different sources, Vodka being readily available and so pure makes it ideal (and cheap). If you do try to test cool but take into effect the skimming very important.
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