The way you say that makes it sound like Kalk doesn't deliver Alkalinity to the tank, which it of course does. Kalk is a well known balanced additive..If you add too much, you will certainly raise both Ca and Alk. It think what you are trying to say is that Kalk isn't really a good choice if one needs to raise Alk independently of Calcium because it will drive both. (Although more of a balanced additive is frequently the real solution to low-alk issues)

As a beginning kalk user, I suggest reading this:
http://www.advancedaquarist.com/issues/feb2003/chem.htm

I think this the key statement from the article:

"The calcium ions in the solution obviously supply calcium to the tank, and the hydroxide ions supply alkalinity. Hydroxide itself provides alkalinity (both by definition and as measured with an alkalinity test), but corals consume alkalinity as bicarbonate, not hydroxide. Fortunately, when limewater is used in a reef tank, it quickly combines with atmospheric and in-tank CO2 and bicarbonate to form bicarbonate and carbonate:"

Yes, my statement is clearly wrong. Sorry about the misconception.
Kalk, or limewater IMO is a MAINTENANCE regime, and not a RAISING method unless you have pretty low take up of calcium in your tanks.
I dose limewater nightly in all my tanks, to replace all evaporated water.
When I want to give a boost to calcium or to alkalinity I use the calcium chloride dowflake and the baked baking soda.